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101.
Three-dimensional (3D) YBO3:Tb3+ flower-like and dense flower-like hierarchitecture constituted of nanoflakes are solvothermally synthesized in the presence of polyborate precursors in the mixture of ethanol and water. The growth process of the YBO3:Tb3+ flowers and dense flowers was explored based on the time-dependent experiment and the results showed that the growth mechanism follows an in situ growth rather than self-assembly process as reported previously. YBO3:Tb3+ morphologies composed of nanoflakes are achieved by controlling the concentration of ethanol and dependence of photoluminescence on morphology was studied. Remarkable photoluminescence enhancement was observed for YBO3:Tb3+ with flower-like morphology demonstrating the potential of the microstructure in future applications as a green phosphor. Such a synthetic method and growth mechanism may be applied to fabricate complex 3D architectures of other materials. 相似文献
102.
广西花山岩体不同风化阶段稀土元素特征及其影响因素 总被引:1,自引:0,他引:1
对广西花山岩体不同风化程度样品的稀土元素特征进行了分析,结果表明,岩体内四个地区的风化程度各异:A区为较强风化,D区和B区为中等风化,C区为中等偏弱风化;稀土含量:A区(886×10-6)D区(660×10-6)B区(524×10-6)C区(424×10-6),与风化程度呈正相关。风化壳剖面A-1中,LREE和HREE均富集在全风化层的下部;剖面D-1中,LREE富集在全风化层上部,HREE则富集在下部。淋滤作用和pH值的变化是稀土元素迁移的基本条件,粘土矿物是元素富集的载体,影响元素分布的主导因素随风化程度而发生变化。当风化程度中等-较低时,LREE的吸附能力大于HREE,致使它们分层富集;当风化程度较高时,LREE浓度不断增大,迁移能力克服了吸附能力,逐渐向下迁移,最终与HREE一起富集在全风化层下部。 相似文献
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106.
利用材料相图及性能模拟软件JMatPro对7050铝合金进行模拟计算,得到7050铝合金的TTT和CCT曲线。合金的TTT曲线整体呈“C”形,GP区、亚稳相和稳定相鼻尖温度分别为140、330、380 ℃,对应的孕育时间为0.002、0.007、0.200 h,η′相无析出的临界冷却速率为2 ℃/s。采用力学性能和电镜组织观察的方法,研究7050铝合金单峰时效热处理工艺。结果表明:当温度达到485 ℃时,在DSC曲线上出现吸热峰;在120 ℃下进行时效处理,随着时效时间的延长,合金的强度硬度持续增加,合金断后伸长率先增加后减小,时效70 h未见过时效特征,当时效8 h时,合金强度和韧性有较好配合,抗拉强度为593 MPa,屈服强度为516 MPa,断后伸长率为12.6%,试样拉伸断口均呈现穿晶韧窝型断裂与沿晶断裂的混合式断口形貌。 相似文献
107.
开展锶(Sr)元素含量及其稳定同位素比值鉴别库尔勒香梨产地的可行性研究,明确新疆库尔勒香梨87Sr/86Sr同位素特征值,为库尔勒香梨产地真实性鉴别提供科学依据。以陕西红香酥梨和甘肃香梨作为对照,借助电感耦合等离子质谱分析新疆库尔勒香梨与对照样品及其对应果园土壤的Sr元素含量,采用多接收器电感耦合等离子质谱分析库尔勒香梨果皮与果肉87Sr/86Sr同位素比值。通过方差分析比较不同产地、不同年际土壤及果实中Sr元素含量的差异,探讨果实与土壤Sr元素含量的相关关系,以及不同产地果实87Sr/86Sr同位素比值与Sr元素含量的分布特征。结果表明:新疆、甘肃、陕西共3 个产地梨园土壤Sr含量存在显著差异(P<0.05),不同年际间梨园土壤Sr含量不存在显著差异。果皮与果肉Sr元素含量存在极显著相关(P<0.01),但二者与土壤Sr元素含量均不存在显著相关。3 个产地梨果肉/果皮Sr含量不存在显著差异。3 个产地87Sr/86Sr同位素比值存在显著差异(P<0.05)。果皮Sr同位素更适合用于库尔勒香梨产地鉴别研究。本实验通过稳定同位素技术为库尔勒香梨产地鉴别提供参考。 相似文献
108.
Zhi Zhou Bianbian Wang Yuan Zhong Wei Zhang Ye Zhang Peixing Gao Nan Zhou 《Ceramics International》2018,44(16):19779-19786
Artificial light source for indoor cultivation has been vastly impeded by the lack of high far red emitting phosphors. Recently, Mn4+ activated phosphors were reported to be promising luminescent materials to solve above matter. In this study, controllable design of Ca14Al10Zn6O35:0.15Mn4+ (CAZO:0.15Mn4+) far red emitting phosphors was realized via pH assisted hydrothermal approach. The pure CAZO:0.15Mn4+ phosphors were obtained merely when the reaction pH was 1 or 2. Meanwhile, by adjusting the pH value of the reaction solution, far red emission CAZO:0.15Mn4+ phosphors with grains, sphere-like as well as aggregated bulk particles can be achieved at pH =?4, pH =?6 and pH =?10, respectively. Furthermore, the structures and morphologies depended photoluminescence (PL) performances of CAZO:0.15Mn4+ were checked. The best PL performance was found for the phosphor produced at pH =?6, while over acidic or alkaline conditions would lower the emission intensity. In addition, this phosphor also exhibit good thermal resistance which can maintain 78% initial intensity at 150?°C. The practical indoor tobacco cultivation demonstrated that CAZO:0.15Mn4+ obtained through this pH adjusted hydrothermal route is a promising phosphor for indoor plant growth lighting. 相似文献
109.
Effect of phytic acid–modified layered double hydroxide on flammability and mechanical properties of intumescent flame retardant polypropylene system 下载免费PDF全文
Ehsan Naderi Kalali Anabel Montes Xin Wang Lu Zhang Marjan E. Shabestari Zhi Li De‐Yi Wang 《火与材料》2018,42(2):213-220
Phytic acid–modified layered double hydroxide (Ph‐LDH) was synthesized via coprecipitation method and subsequently was used in polypropylene (PP) by combining with an ammonium polyphosphate (APP) via melt compounding method. The synergistic effect between APP and Ph‐LDH on the thermal stability, flammability, and mechanical properties of the resultant PP composites was investigated by thermogravimetric analysis, limiting oxygen index, vertical burning test (UL‐94), cone calorimeter tests, tensile test, and impact test. Morphologies of the chars obtained from the samples after the cone calorimeter tests were studied by scanning electron microscopy. The combination of APP and Ph‐LDH slightly influenced the impact and tensile properties of PP. Also, the synergistic effect between APP and Ph‐LDH occurred in the cone calorimeter test. Moreover, the combination of APP and Ph‐LDH produced better quality char that effectively suppressed the spread of the flame and volatile and finally extinguished the fire. 相似文献
110.
Properties of polyamide 6,10/poly(vinyl alcohol) blends and impact on oxygen barrier performance 下载免费PDF全文
Jia‐wei Wu Ya‐qiong Huang Hong‐bo Li James Runt Jen‐taut Yeh 《Polymer International》2018,67(4):453-462
The oxygen transmission rate, average volume of free‐volume cavities (Vf) and fractional free volume (Fv) of polyamide 6,10 (PA610)/poly(vinyl alcohol) (PVA) (i.e. PA610xPVA05y, PA610xPVA08y and PA610xPVA14y) blend films reduced to minimum values when their PVA contents reached corresponding optimal values. Oxygen transmission rate, Vf and Fv values obtained for optimal PA610xPVAzy blown films were reduced considerably with decreasing PVA degrees of polymerization. The oxygen transmission rate of the optimal bio‐based PA61080PVA0520 blown film was only 2.4 cm3 (m2·day·atm)?1, which is about the same as that of the most often used high‐barrier polymer, ethylene–vinyl alcohol copolymer. Experimental findings from dynamic mechanical analysis, differential scanning calorimetry, wide‐angle X‐ray diffraction and Fourier transform infrared spectroscopy of the PA610xPVAzy blends indicate that PA610 and PVA in the blends are miscible to some extent at the molecular level when the PVA contents are less than or equal to the corresponding optimal values. The considerably enhanced oxygen barrier properties of the PA610xPVAzy blend films with optimized compositions are attributed to the significantly reduced local free‐volume characteristics. © 2017 Society of Chemical Industry 相似文献